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Page 1 of 7 SAFETY DATA SHEET Advanced Calibration Designs Inc 2025 W McMillan St Tucson AZ 85705 USA 800 737 0224 www goACD com Product Name HYDROGEN CYANIDE Printing Date 10 10 2018 Revision Date 11 09 2018 1 IDENTIFICATION PRODUCT IDENTIFIER AND CHEMICAL IDENTITY Product Name HYDROGEN CYANIDE Product Code 193 0107 00 Recommended Use of the Chemical and Restriction on Use Industrial use Details of Manufacturer or Importer Phone Number Emergency Telephone Number Advanced Calibration Designs Inc 2024 W McMillan St Tucson AZ 85705 USA 520 290 2855 1 833 737 2444 1 833 737 2444 International 2 HAZARDS IDENTIFICATION Hazardous Nature Label Elements Signal Word Hazard Statements Precautionary Statements Skin Corr Danger 1B H314 Causes severe skin burns and eye damage P260 P280 P264 P303 P361 P353 P305 P351 P338 P321 P304 P340 P363 P301 P330 P331 P310 P405 P501 Do not breathe dust fume gas mist vapors spray Wear protective gloves protective clothing eye protection face protection Wash hands thoroughly after handling IF ON SKIN or hair Remove Take off immediately all contaminated clothing Rinse skin with water shower IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing Specific treatment see on this label IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing Wash contaminated clothing before reuse IF SWALLOWED rinse mouth Do NOT induce vomiting Immediately call a POISON CENTER doctor Store locked up Dispose of contents container in accordance with local regional national regulations 3 COMPOSITION AND INFORMATION ON INGREDIENTS Chemical Characterization Mixtures Description Mixture of substances listed below with nonhazardous additions Hazardous Components 7664 38 2 Phosphoric acid Skin Corr 1B H314 75
Page 2 of 7 SAFETY DATA SHEET Advanced Calibration Designs Inc 2025 W McMillan St Tucson AZ 85705 USA 800 737 0224 www goACD com Product Name HYDROGEN CYANIDE Printing Date 10 10 2018 Revision Date 11 09 2018 Ingestion If swallowed do not induce vomiting Give water milk or milk of magnesia Do not give anything by mouth to an unconscious person Seek immediate medical attention Information for Doctor Symptoms Caused by Exposure Inhalation Burning sensation coughing wheezing laryngitis shortness of breath headache nausea and vomiting Skin Contact Severe irritation or burns Eye Contact Severe irritation or burns Ingestion Severe irritation or burns 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media Use fire extinguishing methods suitable to surrounding conditions Specific Hazards Arising from the Chemical Emits toxic fumes under fire conditions Non combustible liquid Special Protective Equipment and Precautions for Fire Fighters Wear approved self contained breathing apparatus and full protective clothing 6 ACCIDENTAL RELEASE MEASURES Personal Precautions Protective Equipment and Emergency Procedures Wear approved self contained breathing apparatus and full protective clothing Evacuate all non essential personnel from affected area Do not breathe vapors mists Ensure adequate ventilation Environmental Precautions In the event of a major spill prevent spillage from entering drains or water courses Methods and Materials for Containment and Cleaning Up Stop leak if safe to do so and neutralize spill with soda ash or lime Absorb spill with sand earth vermiculite or some other absorbent material Collect the spilled material and place into a suitable container for disposal Provide adequate ventilation Neutralize spill with soda ash or lime 7 HANDLING AND STORAGE Precautions for Safe Handling Use of safe work practices are recommended to avoid eye or skin contact and inhalation of vapors mists Food beverages and tobacco products should not be stored or consumed where this material is in use Always wash hands before smoking eating drinking or using the toilet Wash contaminated clothing and other protective equipment before storage or re use Provide eyewash fountains and safety showers in close proximity to points of potential exposure Conditions for Safe Storage Store in a cool dry and well ventilated area Keep container tightly closed when not in use Keep away from strong bases finely powdered metals Check regularly Protect from physical damage 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Standards 7664 38 2 Phosphoric acid NES STEL 3 mg m TWA 1 mg m Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapor below occupational exposure standards Personal Protective Equipment PPE Respiratory Protection Respiratory protection required if airborne concentration exceeds TLV At concentrations up to 12 ppm a high efficient particulate filter is recommended Above this level a self contained breathing apparatus is advised Skin Protection Polyvinyl alcohol gloves Occupational protective clothing depending on conditions in which it has to be used in particular as regards the period for which it is worn which shall be determined on the basis of the seriousness of the risk the frequency of exposure to the risk the characteristics of the workstation of each worker and the performance of the protective clothing
SAFETY DATA SHEET Advanced Calibration Designs Inc 2025 W McMillan St Tucson AZ 85705 USA 800 737 0224 www goACD com Product Name HYDROGEN CYANIDE Eye and Face Protection Eye and face protectors for protection against splashing materials or liquids Page 3 of 7 Printing Date 10 10 2018 Revision Date 11 09 2018
SAFETY DATA SHEET Advanced Calibration Designs Inc 2025 W McMillan St Tucson AZ 85705 USA 800 737 0224 www goACD com Product Name HYDROGEN CYANIDE Page 4 of 7 Printing Date 10 10 2018 Revision Date 11 09 2018 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Color Odor Odor threshold pH value Melting point melting range Initial boiling point boiling range Flash point Flammability Auto ignition temperature Decomposition temperature Explosion limits Lower Upper Vapor pressure at 20 C Density Relative Density at 20 C Vapor Density at 20 C Evaporation rate Solubility in water Liquid Colorless liquid No information available Not determined 850 mg m rat Acute Health Effects Inhalation May cause severe irritation of the respiratory system Skin May cause severe irritation or burns Eye May cause severe irritation or burns Ingestion May cause severe burns to the mouth esophagus and stomach Skin Corrosion Irritation Causes severe skin burns Serious Eye Damage Irritation Causes serious eye damage Respiratory or Skin Sensitization No sensitizing effects known Germ Cell Mutagenicity Based on classification principles the classification criteria are not met Carcinogenicity This product does NOT contain any IARC listed chemicals Reproductive Toxicity Based on classification principles the classification criteria are not met Specific Target Organ Toxicity STOT Single Exposure Based on classification principles the classification criteria are not met Specific Target Organ Toxicity STOT Repeated Exposure Based on classification principles the classification criteria are not met
SAFETY DATA SHEET Advanced Calibration Designs Inc 2025 W McMillan St Tucson AZ 85705 USA 800 737 0224 www goACD com Product Name HYDROGEN CYANIDE Page 5 of 7 Printing Date 10 10 2018 Revision Date 11 09 2018 Aspiration Hazard Based on classification principles the classification criteria are not met Chronic Health Effects Material is extremely destructive to the mucus membranes and upper respiratory tract eyes and skin Existing Conditions Aggravated by Exposure No information available 12 ECOLOGICAL INFORMATION Eco toxicity No information available Aquatic toxicity No information available Persistence and Degradability No information available Bio accumulative Potential No information available Mobility in Soil No information available 13 DISPOSAL CONSIDERATIONS Disposal Methods and Containers Dispose according to applicable local and state government regulations Special Precautions for Landfill or Incineration Please consult your state Land Waste Management Authority for more information 14 TRANSPORT INFORMATION UN Number ADG IMDG IATA UN1805 Proper Shipping Name ADG IMDG IATA 1805 PHOSPHORIC ACID SOLUTION PHOSPHORIC ACID SOLUTION Dangerous Goods Class ADG Class IMDG Class 8 C1 Corrosive substances 8 Corrosive substances Packing Group ADG IMDG IATA III Marine pollutant No EMS Number F A S B Hazchem Code 2R Special Provisions 223 Limited Quantities 5L Packaging IBCs Packing Instruction P001 IBC03 LP01 Packaging IBCs Special Packing Provisions Not applicable Portable Tanks Bulk Containers Instructions T4 Portable Tanks Bulk Containers Special Provisions TP1 This product meets the limited quantities exception as follows DOT Not regulated as dangerous goods except when transported by air or shipped in quantities greater than or equal to the limited quantity Otherwise the above descriptions apply 15 REGULATORY INFORMATION Inventory of Chemical Substances 7664 38 2 Phosphoric acid
SAFETY DATA SHEET Advanced Calibration Designs Inc 2025 W McMillan St Tucson AZ 85705 USA 800 737 0224 www goACD com Product Name HYDROGEN CYANIDE 7732 18 5 Water Standard for the Uniform Scheduling of Drugs and Poisons SUSMP Poison Schedule Poisons Schedule 6 Page 6 of 7 Printing Date 10 10 2018 Revision Date 11 09 2018
SAFETY DATA SHEET Advanced Calibration Designs Inc 2025 W McMillan St Tucson AZ 85705 USA 800 737 0224 www goACD com Product Name HYDROGEN CYANIDE Page 7 of 7 Printing Date 10 10 2018 Revisoin Date 11 09 2018 16 OTHER INFORMATION Creation Date 10 27 2015 Prepared by Advanced Calibration Designs Inc www goacd com Abbreviations and acronyms GHS Globally Harmonized System of Classification and Labelling of Chemicals EINECS European Inventory of Existing Commercial Chemical Substances ELINCS European List of Notified Chemical Substances CAS Chemical Abstracts Service division of the American Chemical Society VOC Volatile Organic Compounds LC Lethal concentration 50 percent LD Lethal dose 50 percent IARC International Agency for Research on Cancer STEL Short Term Exposure Limit TWA Time Weighted Average NES National Exposure Standard Disclaimer The information contained in this material safety data sheet is provided in good faith and is believed to be accurate at the date of issuance Advanced Calibration Designs Inc makes no representation of the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability for any loss or damage related to the supply or use of the information in this material safety data sheet Advanced Calibration Designs Inc is not in a position to warrant the accuracy of the data herein The user is cautioned to make their own determinations as to the suitability of the information provided to the particular circumstances in which the product is used