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Hydrochloric Acid SDS

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Hydrochloric Acid QCV Safety Data Sheet According To Federal Register Vol 77 No 58 Monday March 26 2012 Rules And Regulations Revision Date 11 09 2018 Date of issue 10 10 2018 Version 1 1 SECTION 1 IDENTIFICATION 1 1 Product Identifier Product Form Mixture Product Name Hydrochloric Acid QCV Product Code 525 0002 01 1 2 Intended Use of the Product Use of the substance mixture No use specified 1 3 Name Address and Telephone of the Responsible Party Company Advanced Calibration Designs Inc 2024 W McMillan Street Tucson Arizona 85705 USA 1 520 290 2855 1 4 Emergency Telephone Number Emergency Number 1 833 737 2444 1 833 737 2444 International SECTION 2 HAZARDS IDENTIFICATION 2 1 Classification of the Substance or Mixture GHS US classification Met Corr 1 H290 Full text of hazard classes and H statements see section 16 2 2 Label Elements GHS US Labeling Hazard Pictograms GHS US GHS05 Signal Word GHS US Hazard Statements GHS US Precautionary Statements GHS US 2 3 Warning H290 May be corrosive to metals P234 Keep only in original container P390 Absorb spillage to prevent material damage P406 Store in corrosive resistant container with a resistant inner liner Other Hazards Exposure may aggravate pre existing eye skin or respiratory conditions 2 4 Unknown Acute Toxicity GHS US No data available SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS 3 1 Substance Not applicable 3 2 Mixture Name Water Hydrochloric acid Product Identifier CAS No 7732 18 5 CAS No 7647 01 0 99 0 1 1 GHS US classification Not classified Met Corr 1 H290 Skin Corr 1B H314 Eye Dam 1 H318 STOT SE 3 H335 Aquatic Acute 2 H401 Full text of H phrases see section 16 SECTION 4 FIRST AID MEASURES 4 1 Description of First Aid Measures First aid Measures General Never give anything by mouth to an unconscious person If you feel unwell seek medical advice show the label where possible 11 09 2018 EN English US 1 6

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Hydrochloric Acid QCV Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations First aid Measures After Inhalation When symptoms occur go into open air and ventilate suspected area Obtain medical attention if breathing difficulty persists First aid Measures After Skin Contact Remove contaminated clothing Drench affected area with water for at least 15 minutes Obtain medical attention if irritation develops or persists First aid Measures After Eye Contact Rinse cautiously with water for at least 15 minutes Remove contact lenses if present and easy to do Continue rinsing Obtain medical attention First aid Measures After Ingestion Rinse mouth Do NOT induce vomiting Obtain medical attention 4 2 Most important symptoms and effects both acute and delayed Symptoms Injuries Not expected to present a significant hazard under anticipated conditions of normal use Symptoms Injuries After Inhalation Prolonged exposure may cause irritation Symptoms Injuries After Skin Contact May cause skin irritation Symptoms Injuries After Eye Contact May cause eye irritation Symptoms Injuries After Ingestion Ingestion is likely to be harmful or have adverse effects Chronic Symptoms None expected under normal conditions of use 4 3 Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned get medical advice and attention If medical advice is needed have product container or label at hand SECTION 5 FIRE FIGHTING MEASURES 5 1 Extinguishing Media Suitable Extinguishing Media Water spray dry chemical foam carbon dioxide Unsuitable Extinguishing Media Do not use a heavy water stream Use of heavy stream of water may spread fire 5 2 Special Hazards Arising From the Substance or Mixture Fire Hazard Not considered flammable Explosion Hazard Contact with metallic substances may release flammable hydrogen gas Reactivity May be corrosive to metals Contact with metals may evolve flammable hydrogen gas 5 3 Advice for Firefighters Precautionary Measures Fire Exercise caution when fighting any chemical fire Firefighting Instructions Use water spray or fog for cooling exposed containers Protection During Firefighting Do not enter fire area without proper protective equipment including respiratory protection SECTION 6 ACCIDENTAL RELEASE MEASURES 6 1 Personal Precautions Protective Equipment and Emergency Procedures General Measures Avoid prolonged contact with eyes skin and clothing Avoid breathing vapor mist spray 6 1 1 For Non emergency Personnel Protective Equipment Use appropriate personal protection equipment PPE Emergency Procedures Evacuate unnecessary personnel 6 1 2 For Emergency Responders Protective Equipment Equip cleanup crew with proper protection Emergency Procedures Upon arrival at the scene a first responder is expected to recognize the presence of dangerous goods protect oneself and the public secure the area and call for the assistance of trained personnel as soon as conditions permit 6 2 Environmental Precautions Prevent entry to sewers and public waters 6 3 Methods and Material for Containment and Cleaning Up For Containment Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams Methods for Cleaning Up Clean up spills immediately and dispose of waste safely Absorb spillage to prevent material damage Transfer spilled material to a suitable container for disposal Contact competent authorities after a spill 6 4 Reference to Other Sections See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations SECTION 7 HANDLING AND STORAGE 7 1 Precautions for Safe Handling Additional Hazards When Processed May be corrosive to metals Precautions for Safe Handling Wash hands and other exposed areas with mild soap and water before eating drinking or smoking and when leaving work Avoid prolonged contact with eyes skin and clothing Avoid breathing vapors mist spray Hygiene Measures Handle in accordance with good industrial hygiene and safety procedures 7 2 Conditions for Safe Storage Including Any Incompatibilities Technical Measures Comply with applicable regulations 11 09 2018 EN English US 2 6

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Hydrochloric Acid QCV Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Storage Conditions Store in corrosive resistant container with a resistant inner liner Keep container closed when not in use Store in a dry cool place Storage areas should be periodically checked for corrosion and integrity Keep Store away from direct sunlight extremely high or low temperatures and incompatible materials Incompatible Products Strong acids strong bases strong oxidizers Packaging materials Store in corrosive resistant container with a resistant inner liner 7 3 Specific End Use s No use specified SECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION 8 1 Control Parameters For substances listed in section 3 that are not listed here there are no established exposure limits from the manufacturer supplier importer or the appropriate advisory agency including ACGIH TLV AIHA WEEL NIOSH REL or OSHA PEL Hydrochloric acid 7647 01 0 USA ACGIH ACGIH Ceiling ppm 2 ppm USA ACGIH ACGIH chemical category Not Classifiable as a Human Carcinogen USA NIOSH NIOSH REL ceiling mg m 7 mg m USA NIOSH NIOSH REL ceiling ppm 5 ppm USA IDLH US IDLH ppm 50 ppm USA OSHA OSHA PEL Ceiling mg m 7 mg m USA OSHA OSHA PEL Ceiling ppm 5 ppm 8 2 Exposure Controls Appropriate Engineering Controls Personal Protective Equipment Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure Ensure adequate ventilation especially in confined areas Ensure all national local regulations are observed Gloves Protective clothing Protective goggles Materials for Protective Clothing Hand Protection Eye Protection Skin and Body Protection Respiratory Protection Other Information Chemically resistant materials and fabrics Wear protective gloves Chemical safety goggles Wear suitable protective clothing If exposure limits are exceeded or irritation is experienced approved respiratory protection should be worn In case of inadequate ventilation or where exposure levels are not known wear approved respiratory protection When using do not eat drink or smoke SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 9 1 Information on Basic Physical and Chemical Properties Physical State Appearance Odor Odor Threshold pH Evaporation Rate Melting Point Freezing Point Boiling Point Flash Point Auto ignition Temperature Decomposition Temperature Flammability solid gas Vapor Pressure Relative Vapor Density at 20 C 11 09 2018 EN English US Liquid Clear No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available 3 6

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Hydrochloric Acid QCV Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Relative Density No data available Solubility Miscible in all portions Partition Coefficient N Octanol Water No data available Viscosity No data available 9 2 Other Information No additional information available SECTION 10 STABILITY AND REACTIVITY 10 1 10 2 10 3 10 4 10 5 10 6 vapors Reactivity May be corrosive to metals Contact with metals may evolve flammable hydrogen gas Chemical Stability Stable under recommended handling and storage conditions see Section 7 Possibility of Hazardous Reactions Hazardous polymerization will not occur Conditions to Avoid Direct sunlight extremely high or low temperatures and incompatible materials Incompatible Materials Strong acids strong bases strong oxidizers Metals May be corrosive to metals Hazardous Decomposition Products Thermal decomposition generates Hydrogen chloride Harmful or irritating SECTION 11 TOXICOLOGICAL INFORMATION 11 1 Information On Toxicological Effects Acute Toxicity Not classified Hydrochloric acid 7647 01 0 LD50 Dermal Rabbit Skin Corrosion Irritation Not classified Serious Eye Damage Irritation Not classified Respiratory or Skin Sensitization Not classified Germ Cell Mutagenicity Not classified Carcinogenicity Not classified 5010 mg kg Hydrochloric acid 7647 01 0 IARC group 3 Reproductive Toxicity Not classified Specific Target Organ Toxicity Single Exposure Not classified Specific Target Organ Toxicity Repeated Exposure Not classified Aspiration Hazard Not classified Symptoms Injuries After Inhalation Prolonged exposure may cause irritation Symptoms Injuries After Skin Contact May cause skin irritation Symptoms Injuries After Eye Contact May cause eye irritation Symptoms Injuries After Ingestion Ingestion is likely to be harmful or have adverse effects Chronic Symptoms None expected under normal conditions of use SECTION 12 ECOLOGICAL INFORMATION 12 1 Toxicity Ecology General Hydrochloric acid 7647 01 0 LC50 Fish 1 12 2 Not established Bioaccumulative Potential Hydrochloric Acid QCV Bioaccumulative Potential 12 4 12 5 7 45 mg l Species Oncorhynchus mykiss Exposure time 96h Persistence and Degradability Hydrochloric Acid QCV Persistence and Degradability 12 3 Not classified Not established Mobility in Soil No additional information available Other Adverse Effects Other Information Avoid release to the environment SECTION 13 DISPOSAL CONSIDERATIONS 13 1 Waste treatment methods Waste Disposal Recommendations Dispose of contents container in accordance with local regional national and international regulations 11 09 2018 EN English US 4 6

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Hydrochloric Acid QCV Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Additional Information Container may remain hazardous when empty Continue to observe all precautions Ecology Waste Materials Avoid release to the environment SECTION 14 TRANSPORT INFORMATION 14 1 In Accordance with DOT Proper Shipping Name Hazard Class Identification Number Label Codes HYDROCHLORIC ACID SOLUTION 8 UN1789 8 Packing Group ERG Number III 157 14 2 In Accordance with IMDG Proper Shipping Name Hazard Class Identification Number Packing Group Label Codes EmS No Fire EmS No Spillage HYDROCHLORIC ACID SOLUTION 8 UN1789 III 8 F A S B 14 3 In Accordance with IATA Proper Shipping Name Identification Number Hazard Class Label Codes ERG Code IATA 8L Packing Group HYDROCHLORIC ACID SOLUTION III UN1789 8 8 SECTION 15 REGULATORY INFORMATION 15 1 US Federal Regulations Hydrochloric acid 7647 01 0 Listed on the United States TSCA Toxic Substances Control Act inventory Listed on the United States SARA Section 302 Subject to reporting requirements of United States SARA Section 313 SARA Section 302 Threshold Planning Quantity TPQ 500 gas only SARA Section 313 Emission Reporting 1 0 acid aerosols including mists vapors gas fog and other airborne forms of any particle size Water 7732 18 5 Listed on the United States TSCA Toxic Substances Control Act inventory 15 2 US State Regulations Hydrochloric acid 7647 01 0 U S Massachusetts Right To Know List U S New Jersey Right to Know Hazardous Substance List U S Pennsylvania RTK Right to Know Environmental Hazard List U S Pennsylvania RTK Right to Know List SECTION 16 OTHER INFORMATION INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date Other Information 03 23 2016 This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910 1200 GHS Full Text Phrases Aquatic Acute 2 Eye Dam 1 Met Corr 1 Skin Corr 1B STOT SE 3 11 09 2018 Hazardous to the aquatic environment Acute Hazard Category 2 Serious eye damage eye irritation Category 1 Corrosive to metals Category 1 Skin corrosion irritation Category 1B Specific target organ toxicity single exposure Category 3 EN English US 5 6

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Hydrochloric Acid QCV Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations H290 H314 H318 H335 H401 May be corrosive to metals Causes severe skin burns and eye damage Causes serious eye damage May cause respiratory irritation Toxic to aquatic life This information is based on our current knowledge and is intended to describe the product for the purposes of health safety and environmental requirements only It should not therefore be construed as guaranteeing any specific property of the product SDS US GHS HazCom 11 09 2018 EN English US 6 6