Chlorine Dioxide Electrolyte Liquid Safety Data Sheet According To Federal Register Vol 77 No 58 Monday March 26 2012 Rules And Regulations Revision Date 11 09 2018 Date of issue 10 10 2018 Version 1 1 SECTION 1 IDENTIFICATION 1 1 Product Identifier Product Form Mixture Product Name Chlorine Dioxide Electrolyte Liquid 1 2 Intended Use of the Product Use of the substance mixture No use specified 1 3 Name Address and Telephone of the Responsible Party Company Advanced Calibration Designs Inc 2024 W McMillan Street Tucson Arizona 85705 USA 1 520 290 2855 1 4 Emergency Telephone Number 1 833 737 2444 1 833 737 2444 International Emergency Number SECTION 2 HAZARDS IDENTIFICATION 2 1 Classification of the Substance or Mixture GHS US classification Aquatic Acute 2 H401 Full text of hazard classes and H statements see section 16 2 2 Label Elements GHS US Labeling Hazard Statements GHS US Precautionary Statements GHS US 2 3 H401 Toxic to aquatic life P273 Avoid release to the environment P501 Dispose of contents container in accordance with local regional national and international regulations Other Hazards Exposure may aggravate pre existing eye skin or respiratory conditions 2 4 Unknown Acute Toxicity GHS US No data available SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS 3 1 Substance Not applicable 3 2 Mixture Name Water Sodium chlorite Product Identifier CAS No 7732 18 5 CAS No 7758 19 2 99 0 01 1 GHS US classification Not classified Ox Sol 1 H271 Acute Tox 3 Oral H301 Acute Tox 2 Dermal H310 Acute Tox 2 Inhalation dust mist H330 Skin Corr 1B H314 Eye Dam 1 H318 STOT RE 2 H373 Aquatic Acute 1 H400 Aquatic Chronic 3 H412 Full text of H phrases see section 16 SECTION 4 FIRST AID MEASURES 4 1 Description of First Aid Measures First aid Measures General Never give anything by mouth to an unconscious person If you feel unwell seek medical advice show the label where possible First aid Measures After Inhalation When symptoms occur go into open air and ventilate suspected area Obtain medical attention if breathing difficulty persists First aid Measures After Skin Contact Remove contaminated clothing Drench affected area with water for at least 15 minutes Obtain medical attention if irritation develops or persists 11 09 2018 EN English US 1 6
Chlorine Dioxide Electrolyte Liquid Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations First aid Measures After Eye Contact Rinse cautiously with water for at least 15 minutes Remove contact lenses if present and easy to do Continue rinsing Obtain medical attention First aid Measures After Ingestion Rinse mouth Do NOT induce vomiting Obtain medical attention 4 2 Most important symptoms and effects both acute and delayed Symptoms Injuries Not expected to present a significant hazard under anticipated conditions of normal use Toxic and corrosive gas may be generated upon oxidization or upon contact with incompatibe materials Symptoms Injuries After Inhalation Prolonged exposure may cause irritation Symptoms Injuries After Skin Contact May cause skin irritation Symptoms Injuries After Eye Contact May cause eye irritation Symptoms Injuries After Ingestion Ingestion is likely to be harmful or have adverse effects Chronic Symptoms None expected under normal conditions of use 4 3 Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned get medical advice and attention If medical advice is needed have product container or label at hand SECTION 5 FIRE FIGHTING MEASURES 5 1 Extinguishing Media Suitable Extinguishing Media Water spray dry chemical foam carbon dioxide Unsuitable Extinguishing Media Do not use a heavy water stream Use of heavy stream of water may spread fire 5 2 Special Hazards Arising From the Substance or Mixture Fire Hazard Not considered flammable but may burn at high temperatures Avoid evaporation to dryness Dried material can ignite upon contact with combustibles Explosion Hazard Product is not explosive but may evolve explosive chlorine dioxide gas when pressurized or heated Heat may build pressure rupturing closed containers spreading fire and increasing risk of burns and injuries Reactivity May form explosive chlorine dioxide gas on contact with incompatible materials such as acid 5 3 Advice for Firefighters Precautionary Measures Fire Exercise caution when fighting any chemical fire Firefighting Instructions Use water spray or fog for cooling exposed containers Protection During Firefighting Do not enter fire area without proper protective equipment including respiratory protection Other Information Do not allow run off from fire fighting to enter drains or water courses SECTION 6 ACCIDENTAL RELEASE MEASURES 6 1 Personal Precautions Protective Equipment and Emergency Procedures General Measures Avoid prolonged contact with eyes skin and clothing Avoid breathing vapor mist spray 6 1 1 For Non emergency Personnel Protective Equipment Use appropriate personal protection equipment PPE Emergency Procedures Evacuate unnecessary personnel 6 1 2 For Emergency Responders Protective Equipment Equip cleanup crew with proper protection Emergency Procedures Upon arrival at the scene a first responder is expected to recognize the presence of dangerous goods protect oneself and the public secure the area and call for the assistance of trained personnel as soon as conditions permit 6 2 Environmental Precautions Prevent entry to sewers and public waters Avoid release to the environment 6 3 Methods and Material for Containment and Cleaning Up For Containment Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams Methods for Cleaning Up Clean up spills immediately and dispose of waste safely Transfer spilled material to a suitable container for disposal Contact competent authorities after a spill 6 4 Reference to Other Sections See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations SECTION 7 HANDLING AND STORAGE 7 1 Precautions for Safe Handling Additional Hazards When Processed May release corrosive and flammable gas Precautions for Safe Handling Wash hands and other exposed areas with mild soap and water before eating drinking or smoking and when leaving work Keep away from heat sparks open flames hot surfaces combustible materials incompatible materials No smoking Avoid prolonged contact with eyes skin and clothing Avoid breathing vapors mist spray Hygiene Measures Handle in accordance with good industrial hygiene and safety procedures 7 2 Conditions for Safe Storage Including Any Incompatibilities Technical Measures Comply with applicable regulations 11 09 2018 EN English US 2 6
Chlorine Dioxide Electrolyte Liquid Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Storage Conditions Keep container closed when not in use Store in a dry cool place Keep Store away from direct sunlight extremely high or low temperatures and incompatible materials Incompatible Products Strong acids strong bases strong oxidizers 7 3 Specific End Use s No use specified SECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION 8 1 Control Parameters For substances listed in section 3 that are not listed here there are no established exposure limits from the manufacturer supplier importer or the appropriate advisory agency including ACGIH TLV AIHA WEEL NIOSH REL or OSHA PEL 8 2 Exposure Controls Appropriate Engineering Controls Personal Protective Equipment Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure Ensure adequate ventilation especially in confined areas Gas detectors should be used when flammable gases or vapors may be released Gas detectors should be used when toxic gases may be released Ensure all national local regulations are observed Gloves Protective clothing Protective goggles Materials for Protective Clothing Hand Protection Eye Protection Skin and Body Protection Respiratory Protection Other Information Chemically resistant materials and fabrics Wear protective gloves Chemical safety goggles Wear suitable protective clothing If exposure limits are exceeded or irritation is experienced approved respiratory protection should be worn In case of inadequate ventilation or where exposure levels are not known wear approved respiratory protection When using do not eat drink or smoke SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 9 1 Information on Basic Physical and Chemical Properties Physical State Appearance Odor Odor Threshold pH Evaporation Rate Melting Point Freezing Point Boiling Point Flash Point Auto ignition Temperature Decomposition Temperature Flammability solid gas Vapor Pressure Relative Vapor Density at 20 C Relative Density Solubility Partition Coefficient N Octanol Water Viscosity 11 09 2018 EN English US Liquid Clear Odorless No data available No data available No data available No data available 12 C 10 4 F 110 C 230 F No data available No data available No data available No data available 760 mm Hg at 100 C 212 F No data available 1 Water 1 Salts approximately 15 in cold water No data available No data available 3 6
Chlorine Dioxide Electrolyte Liquid Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations 9 2 Other Information No additional information available SECTION 10 STABILITY AND REACTIVITY 10 1 Reactivity May form explosive chlorine dioxide gas on contact with incompatible materials such as acid 10 2 Chemical Stability Stable under recommended handling and storage conditions see Section 7 10 3 Possibility of Hazardous Reactions Hazardous polymerization will not occur 10 4 Conditions to Avoid Direct sunlight extremely high or low temperatures and incompatible materials 10 5 Incompatible Materials Strong acids strong bases strong oxidizers 10 6 Hazardous Decomposition Products Thermal decomposition generates Sodium oxides Chlorine dioxide Chlorine Harmful or irritating fumes SECTION 11 TOXICOLOGICAL INFORMATION 11 1 Information On Toxicological Effects Acute Toxicity Not classified Sodium chlorite 7758 19 2 LD50 Oral Rat LD50 Dermal Rabbit LC50 Inhalation Rat LC50 Inhalation Rat Skin Corrosion Irritation Not classified Serious Eye Damage Irritation Not classified Respiratory or Skin Sensitization Not classified Germ Cell Mutagenicity Not classified Carcinogenicity Not classified 165 mg kg 107 2 mg kg 230 mg m Exposure time 4 h 0 23 mg l 4h Sodium chlorite 7758 19 2 IARC group 3 Reproductive Toxicity Not classified Specific Target Organ Toxicity Single Exposure Not classified Specific Target Organ Toxicity Repeated Exposure Not classified Aspiration Hazard Not classified Symptoms Injuries After Inhalation Prolonged exposure may cause irritation Symptoms Injuries After Skin Contact May cause skin irritation Symptoms Injuries After Eye Contact May cause eye irritation Symptoms Injuries After Ingestion Ingestion is likely to be harmful or have adverse effects Chronic Symptoms None expected under normal conditions of use SECTION 12 ECOLOGICAL INFORMATION 12 1 Toxicity Ecology General Sodium chlorite 7758 19 2 LC50 Fish 1 EC50 Daphnia 1 LC 50 Fish 2 EC50 Daphnia 2 12 2 Not established Mobility in Soil No additional information available Other Adverse Effects Other Information 11 09 2018 Not established Bioaccumulative Potential Chlorine Dioxide Electrolyte Liquid Bioaccumulative Potential 12 4 12 5 100 500 mg l Exposure time 96 h Species Brachydanio rerio static 0 026 mg l Exposure time 48 h Species Daphnia magna 100 mg l Exposure time 96 h Species Lepomis macrochirus static 0 25 0 33 mg l Exposure time 48 h Species Daphnia magna Flow through Persistence and Degradability Chlorine Dioxide Electrolyte Liquid Persistence and Degradability 12 3 Toxic to aquatic life Avoid release to the environment EN English US 4 6
Chlorine Dioxide Electrolyte Liquid Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations SECTION 13 DISPOSAL CONSIDERATIONS 13 1 Waste treatment methods Waste Disposal Recommendations Dispose of contents container in accordance with local regional national and international regulations Additional Information Container may remain hazardous when empty Continue to observe all precautions Ecology Waste Materials Avoid release to the environment This material is hazardous to the aquatic environment Keep out of sewers and waterways SECTION 14 TRANSPORT INFORMATION 14 1 In Accordance with DOT Proper Shipping Name Hazard Class Identification Number Label Codes ENVIRONMENTALLY HAZARDOUS SUBSTANCES LIQUID N O S Contains Sodium chlorite 9 UN3082 9 Packing Group ERG Number III 171 14 2 In Accordance with IMDG Proper Shipping Name Hazard Class Identification Number Packing Group Label Codes EmS No Fire EmS No Spillage ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N O S Contains Sodium chlorite 9 UN3082 III 9 F A S F 14 3 In Accordance with IATA Proper Shipping Name Identification Number Hazard Class Label Codes ERG Code IATA 9L Packing Group ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N O S Contains Sodium chlorite III UN3082 9 9 SECTION 15 REGULATORY INFORMATION 15 1 US Federal Regulations Sodium chlorite 7758 19 2 Listed on the United States TSCA Toxic Substances Control Act inventory Water 7732 18 5 Listed on the United States TSCA Toxic Substances Control Act inventory 15 2 US State Regulations Sodium chlorite 7758 19 2 U S Massachusetts Right To Know List U S New Jersey Right to Know Hazardous Substance List U S Pennsylvania RTK Right to Know List SECTION 16 OTHER INFORMATION INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date Other Information 03 23 2016 This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910 1200 GHS Full Text Phrases Acute Tox 2 Dermal Acute Tox 2 Inhalation dust mist Acute Tox 3 Oral Aquatic Acute 1 Aquatic Acute 2 Aquatic Chronic 3 11 09 2018 Acute toxicity dermal Category 2 Acute toxicity inhalation dust mist Category 2 Acute toxicity oral Category 3 Hazardous to the aquatic environment Acute Hazard Category 1 Hazardous to the aquatic environment Acute Hazard Category 2 Hazardous to the aquatic environment Chronic Hazard Category 3 EN English US 5 6
Chlorine Dioxide Electrolyte Liquid Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Eye Dam 1 Ox Sol 1 Skin Corr 1B STOT RE 2 H271 H301 H310 H314 H318 H330 H373 H400 H401 H412 Serious eye damage eye irritation Category 1 Oxidizing solids Category 1 Skin corrosion irritation Category 1B Specific target organ toxicity repeated exposure Category 2 May cause fire or explosion strong oxidizer Toxic if swallowed Fatal in contact with skin Causes severe skin burns and eye damage Causes serious eye damage Fatal if inhaled May cause damage to organs through prolonged or repeated exposure Very toxic to aquatic life Toxic to aquatic life Harmful to aquatic life with long lasting effects This information is based on our current knowledge and is intended to describe the product for the purposes of health safety and environmental requirements only It should not therefore be construed as guaranteeing any specific property of the product SDS US GHS HazCom 11 09 2018 EN English US 6 6