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QCV Ammonia Solution SDS

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QCV Ammonia Solution Safety Data Sheet According To Federal Register Vol 77 No 58 Monday March 26 2012 Rules And Regulations Revision Date 11 09 2018 Date of issue 10 10 2018 Version 1 1 SECTION 1 IDENTIFICATION 1 1 Product Identifier Product Form Mixture Product Name QCV Ammonia Solution Product Code 525 0001 01 Synonyms Ammonium Hydroxide Solution 1 2 Intended Use of the Product Use of the substance mixture No use specified 1 3 Name Address and Telephone of the Responsible Party Company Advanced Calibration Designs Inc 2024 W McMillan Street Tucson Arizona 85705 USA 1 520 290 2855 1 4 Emergency Telephone Number Emergency Number 1 833 737 2444 1 833 737 2444 International SECTION 2 HAZARDS IDENTIFICATION 2 1 Classification of the Substance or Mixture GHS US classification Skin Corr 1B H314 Eye Dam 1 H318 STOT SE 3 H335 Aquatic Acute 2 H401 Aquatic Chronic 3 H412 Full text of hazard classes and H statements see section 16 2 2 Label Elements GHS US Labeling Hazard Pictograms GHS US Signal Word GHS US Hazard Statements GHS US Danger H314 Causes severe skin burns and eye damage H335 May cause respiratory irritation H401 Toxic to aquatic life H412 Harmful to aquatic life with long lasting effects P260 Do not breathe vapors mist or spray P264 Wash hands forearms and other exposed areas thoroughly after handling P271 Use only outdoors or in a well ventilated area P273 Avoid release to the environment P280 Wear protective gloves protective clothing and eye protection P301 P330 P331 If swallowed rinse mouth Do NOT induce vomiting P303 P361 P353 If on skin or hair Take off immediately all contaminated clothing Rinse skin with water shower P304 P340 If inhaled Remove person to fresh air and keep at rest in a position comfortable for breathing P305 P351 P338 If in eyes Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P310 Immediately call a poison center or doctor P321 Specific treatment see section 4 on this SDS P363 Wash contaminated clothing before reuse P403 P233 Store in a well ventilated place Keep container tightly closed P405 Store locked up P501 Dispose of contents container in accordance with local regional national GHS05 Precautionary Statements GHS US 11 09 2018 EN English US GHS07 1 7

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QCV Ammonia Solution Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations and international regulations 2 3 Other Hazards Exposure may aggravate pre existing eye skin or respiratory conditions 2 4 Unknown Acute Toxicity GHS US No data available SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS 3 1 Substance Not applicable 3 2 Mixture Name Water Ammonia Product Identifier CAS No 7732 18 5 CAS No 7664 41 7 90 0 1 10 GHS US classification Not classified Flam Gas 2 H221 Liquefied gas H280 Acute Tox 3 Inhalation gas H331 Skin Corr 1B H314 Eye Dam 1 H318 STOT SE 3 H335 Aquatic Acute 1 H400 Aquatic Chronic 2 H411 Full text of H phrases see section 16 SECTION 4 FIRST AID MEASURES 4 1 Description of First Aid Measures First aid Measures General Never give anything by mouth to an unconscious person If you feel unwell seek medical advice show the label where possible First aid Measures After Inhalation When symptoms occur go into open air and ventilate suspected area Obtain medical attention if breathing difficulty persists First aid Measures After Skin Contact Remove contaminated clothing Immediately flush skin with plenty of water for at least 60 minutes Wash contaminated clothing before reuse Immediately call a POISON CENTER or doctor First aid Measures After Eye Contact Rinse cautiously with water for at least 60 minutes Remove contact lenses if present and easy to do Continue rinsing Get immediate medical advice attention First aid Measures After Ingestion Rinse mouth Do NOT induce vomiting Obtain medical attention 4 2 Most important symptoms and effects both acute and delayed Symptoms Injuries May cause respiratory irritation Causes severe skin burns and eye damage Causes serious eye damage Symptoms Injuries After Inhalation May be corrosive to the respiratory tract Symptoms Injuries After Skin Contact Causes severe irritation which will progress to chemical burns Symptoms Injuries After Eye Contact Causes permanent damage to the cornea iris or conjunctiva Symptoms Injuries After Ingestion May cause burns or irritation of the linings of the mouth throat and gastrointestinal tract Chronic Symptoms None expected under normal conditions of use 4 3 Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned get medical advice and attention If medical advice is needed have product container or label at hand SECTION 5 FIRE FIGHTING MEASURES 5 1 Extinguishing Media Suitable Extinguishing Media Water spray dry chemical foam carbon dioxide Unsuitable Extinguishing Media Do not use a heavy water stream Use of heavy stream of water may spread fire 5 2 Special Hazards Arising From the Substance or Mixture Fire Hazard Not considered flammable Explosion Hazard Product is not explosive Reactivity May react exothermically with water releasing heat Adding an acid to a base or base to an acid may cause a violent reaction 5 3 Advice for Firefighters Precautionary Measures Fire Exercise caution when fighting any chemical fire Firefighting Instructions Use water spray or fog for cooling exposed containers Protection During Firefighting Do not enter fire area without proper protective equipment including respiratory protection Other Information Do not allow run off from fire fighting to enter drains or water courses 11 09 2018 EN English US 2 7

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QCV Ammonia Solution Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations SECTION 6 ACCIDENTAL RELEASE MEASURES 6 1 Personal Precautions Protective Equipment and Emergency Procedures General Measures Do not get in eyes on skin or on clothing Do not breathe vapor mist or spray 6 1 1 For Non emergency Personnel Protective Equipment Use appropriate personal protection equipment PPE Emergency Procedures Evacuate unnecessary personnel 6 1 2 For Emergency Responders Protective Equipment Equip cleanup crew with proper protection Emergency Procedures Upon arrival at the scene a first responder is expected to recognize the presence of dangerous goods protect oneself and the public secure the area and call for the assistance of trained personnel as soon as conditions permit 6 2 Environmental Precautions Prevent entry to sewers and public waters Avoid release to the environment 6 3 Methods and Material for Containment and Cleaning Up For Containment Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams As an immediate precautionary measure isolate spill or leak area in all directions Methods for Cleaning Up Clean up spills immediately and dispose of waste safely Cautiously neutralize spilled liquid Transfer spilled material to a suitable container for disposal Contact competent authorities after a spill 6 4 Reference to Other Sections See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations SECTION 7 HANDLING AND STORAGE 7 1 Precautions for Safe Handling Additional Hazards When Processed May release corrosive vapors Precautions for Safe Handling Wash hands and other exposed areas with mild soap and water before eating drinking or smoking and when leaving work Handle empty containers with care because they may still present a hazard Do not get in eyes on skin or on clothing Do not breathe gas mist vapors spray Hygiene Measures Handle in accordance with good industrial hygiene and safety procedures 7 2 Conditions for Safe Storage Including Any Incompatibilities Technical Measures Comply with applicable regulations Storage Conditions Store in original container or corrosive resistant and or lined container Keep container closed when not in use Store in a dry cool place Keep Store away from direct sunlight extremely high or low temperatures and incompatible materials Incompatible Products Strong acids strong bases strong oxidizers 7 3 Specific End Use s No use specified SECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION 8 1 Control Parameters For substances listed in section 3 that are not listed here there are no established exposure limits from the manufacturer supplier importer or the appropriate advisory agency including ACGIH TLV AIHA WEEL NIOSH REL or OSHA PEL Ammonia 7664 41 7 USA ACGIH ACGIH TWA ppm 25 ppm USA ACGIH ACGIH STEL ppm 35 ppm USA NIOSH NIOSH REL TWA mg m 18 mg m USA NIOSH NIOSH REL TWA ppm 25 ppm USA NIOSH NIOSH REL STEL mg m 27 mg m USA NIOSH NIOSH REL STEL ppm 35 ppm USA IDLH US IDLH ppm 300 ppm USA OSHA OSHA PEL TWA mg m 35 mg m USA OSHA OSHA PEL TWA ppm 50 ppm 8 2 Exposure Controls Appropriate Engineering Controls 11 09 2018 Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure Ensure adequate ventilation especially in confined areas Ensure all national local regulations are observed EN English US 3 7

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QCV Ammonia Solution Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Personal Protective Equipment Gloves Protective clothing Protective goggles Face shield Insufficient ventilation wear respiratory protection Materials for Protective Clothing Hand Protection Eye Protection Skin and Body Protection Respiratory Protection Other Information Chemically resistant materials and fabrics Corrosion proof clothing Wear protective gloves Chemical goggles or face shield Wear suitable protective clothing If exposure limits are exceeded or irritation is experienced approved respiratory protection should be worn In case of inadequate ventilation or where exposure levels are not known wear approved respiratory protection When using do not eat drink or smoke SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 9 1 Information on Basic Physical and Chemical Properties Physical State Liquid Appearance Colorless Odor Intense pungent Odor Threshold No data available pH No data available Evaporation Rate No data available Melting Point No data available Freezing Point No data available Boiling Point 38 C 100 F Flash Point No data available Auto ignition Temperature No data available Decomposition Temperature No data available Flammability solid gas No data available Vapor Pressure No data available Relative Vapor Density at 20 C No data available Relative Density No data available Solubility Miscible Partition Coefficient N Octanol Water No data available Viscosity No data available 9 2 Other Information No additional information available SECTION 10 STABILITY AND REACTIVITY 10 1 Reactivity May react exothermically with water releasing heat Adding an acid to a base or base to an acid may cause a violent reaction 10 2 Chemical Stability Stable under recommended handling and storage conditions see section 7 10 3 Possibility of Hazardous Reactions Hazardous polymerization will not occur 10 4 Conditions to Avoid Direct sunlight extremely high or low temperatures and incompatible materials 10 5 Incompatible Materials Strong acids strong bases strong oxidizers 10 6 Hazardous Decomposition Products Thermal decomposition generates Ammonia gas Corrosive vapors SECTION 11 TOXICOLOGICAL INFORMATION 11 1 Information On Toxicological Effects Acute Toxicity Not classified Ammonia 7664 41 7 LD50 Oral Rat 350 mg kg LC50 Inhalation Rat 5 1 mg l Exposure time 1 h LC50 Inhalation Rat 2000 ppm 4h Exposure time 4 h Skin Corrosion Irritation Causes severe skin burns and eye damage 11 09 2018 EN English US 4 7

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QCV Ammonia Solution Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Serious Eye Damage Irritation Causes serious eye damage Respiratory or Skin Sensitization Not classified Germ Cell Mutagenicity Not classified Carcinogenicity Not classified Reproductive Toxicity Not classified Specific Target Organ Toxicity Single Exposure May cause respiratory irritation Specific Target Organ Toxicity Repeated Exposure Not classified Aspiration Hazard Not classified Symptoms Injuries After Inhalation May be corrosive to the respiratory tract Symptoms Injuries After Skin Contact Causes severe irritation which will progress to chemical burns Symptoms Injuries After Eye Contact Causes permanent damage to the cornea iris or conjunctiva Symptoms Injuries After Ingestion May cause burns or irritation of the linings of the mouth throat and gastrointestinal tract Chronic Symptoms None expected under normal conditions of use SECTION 12 ECOLOGICAL INFORMATION 12 1 Toxicity Ecology General Ammonia 7664 41 7 LC50 Fish 1 EC50 Daphnia 1 LC 50 Fish 2 12 2 Toxic to aquatic life Harmful to aquatic life with long lasting effects 0 44 mg l Exposure time 96 h Species Cyprinus carpio 25 4 mg l Exposure time 48 h Species Daphnia magna 0 26 4 6 mg l Exposure time 96 h Species Lepomis macrochirus Persistence and Degradability QCV Ammonia Solution Persistence and Degradability 12 3 May cause long term adverse effects in the environment Bioaccumulative Potential QCV Ammonia Solution Bioaccumulative Potential Ammonia 7664 41 7 Log Pow 12 4 12 5 Not established 1 14 at 25 C Mobility in Soil No additional information available Other Adverse Effects Other Information Avoid release to the environment SECTION 13 DISPOSAL CONSIDERATIONS 13 1 Waste treatment methods Waste Disposal Recommendations Dispose of contents container in accordance with local regional national and international regulations Additional Information Container may remain hazardous when empty Continue to observe all precautions Ecology Waste Materials Avoid release to the environment This material is hazardous to the aquatic environment Keep out of sewers and waterways SECTION 14 TRANSPORT INFORMATION 14 1 In Accordance with DOT Proper Shipping Name Hazard Class Identification Number Label Codes Packing Group ERG Number II 154 11 09 2018 CORROSIVE LIQUIDS N O S Contains Ammonia 8 UN1760 8 EN English US 5 7

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QCV Ammonia Solution Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations 14 2 In Accordance with IMDG Proper Shipping Name Hazard Class Identification Number Packing Group Label Codes EmS No Fire EmS No Spillage CORROSIVE LIQUID N O S Contains Ammonia 8 UN1760 II 8 F A S B 14 3 In Accordance with IATA Proper Shipping Name Identification Number Hazard Class Label Codes ERG Code IATA 8L Packing Group CORROSIVE LIQUID N O S Contains Ammonia II UN1760 8 8 SECTION 15 REGULATORY INFORMATION 15 1 US Federal Regulations QCV Ammonia Solution SARA Section 311 312 Hazard Classes Immediate acute health hazard Ammonia 7664 41 7 Listed on the United States TSCA Toxic Substances Control Act inventory Listed on the United States SARA Section 302 Subject to reporting requirements of United States SARA Section 313 SARA Section 302 Threshold Planning Quantity TPQ 500 SARA Section 313 Emission Reporting 1 0 includes anhydrous Ammonia and aqueous Ammonia from water dissociable Ammonium salts and other sources 10 of total aqueous Ammonia is reportable under this listing Water 7732 18 5 Listed on the United States TSCA Toxic Substances Control Act inventory 15 2 US State Regulations Ammonia 7664 41 7 U S Massachusetts Right To Know List U S New Jersey Right to Know Hazardous Substance List U S Pennsylvania RTK Right to Know Environmental Hazard List U S Pennsylvania RTK Right to Know List SECTION 16 OTHER INFORMATION INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date Other Information 03 23 2016 This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910 1200 GHS Full Text Phrases Acute Tox 3 Inhalation gas Aquatic Acute 1 Aquatic Acute 2 Aquatic Chronic 2 Aquatic Chronic 3 Eye Dam 1 Flam Gas 2 Liquefied gas Skin Corr 1B STOT SE 3 H221 H280 11 09 2018 Acute toxicity inhalation gas Category 3 Hazardous to the aquatic environment Acute Hazard Category 1 Hazardous to the aquatic environment Acute Hazard Category 2 Hazardous to the aquatic environment Chronic Hazard Category 2 Hazardous to the aquatic environment Chronic Hazard Category 3 Serious eye damage eye irritation Category 1 Flammable gases Category 2 Gases under pressure Liquefied gas Skin corrosion irritation Category 1B Specific target organ toxicity single exposure Category 3 Flammable gas Contains gas under pressure may explode if heated EN English US 6 7

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QCV Ammonia Solution Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations H314 H318 H331 H335 H400 H401 H411 H412 Causes severe skin burns and eye damage Causes serious eye damage Toxic if inhaled May cause respiratory irritation Very toxic to aquatic life Toxic to aquatic life Toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects This information is based on our current knowledge and is intended to describe the product for the purposes of health safety and environmental requirements only It should not therefore be construed as guaranteeing any specific property of the product SDS US GHS HazCom 11 09 2018 EN English US 7 7