Chlorine Electrolyte Safety Data Sheet According To Federal Register Vol 77 No 58 Monday March 26 2012 Rules And Regulations Date of Revision 11 09 2018 Date of Issue 10 10 2018 Version 1 1 SECTION 1 IDENTIFICATION 1 1 Product Identifier 1 2 Intended Use of the Product 1 3 Name Address and Telephone of the Responsible Party 1 4 Emergency Telephone Number Product Form Mixture Product Name Chlorine Electrolyte Use of the Substance Mixture Industrial Use Company Advanced Calibration Designs Inc 2024 W McMillan Street Tucson Arizona 85705 USA 1 520 290 2855 Emergency Number 1 833 737 2444 1 833 737 2444 International SECTION 2 HAZARDS IDENTIFICATION 2 1 Classification of the Substance or Mixture GHS US Classification Met Corr 1 H290 Skin Irrit 2 H315 Eye Dam 1 H318 Full text of hazard classes and H statements see Section 16 2 2 Label Elements GHS US Labeling Hazard Pictograms GHS US Signal Word GHS US Hazard Statements GHS US Danger H290 May be corrosive to metals H315 Causes skin irritation H318 Causes serious eye damage P234 Keep only in original container P264 Wash hands forearms and other exposed areas thoroughly after handling P280 Wear protective gloves protective clothing and eye protection P302 P352 If on skin Wash with plenty of water P305 P351 P338 If in eyes Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P310 Immediately call a poison center or doctor P321 Specific treatment see Section 4 on this SDS P332 P313 If skin irritation occurs Get medical advice attention P362 P364 Take off contaminated clothing and wash it before reuse P390 Absorb spillage to prevent material damage P406 Store in corrosive resistant container with a resistant inner liner Precautionary Statements GHS US GHS05 2 3 Other Hazards 2 4 Unknown Acute Toxicity GHS US Exposure may aggravate pre existing eye skin or respiratory conditions No data available SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS 3 2 Mixture Name Water 11 09 2018 Product Identifier CAS No 7732 18 5 EN English US 97 24174 98 36674 GHS US classification Not classified 1 7
Chlorine Electrolyte Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Lithium chloride CAS No 7447 41 8 1 125 2 25 Copper 2 chloride dihydrate CAS No 10125 13 0 0 5 Hydrochloric acid CAS No 7647 01 0 0 00826 Acute Tox 4 Oral H302 Skin Irrit 2 H315 Eye Irrit 2A H319 Aquatic Acute 3 H402 Acute Tox 4 Oral H302 Acute Tox 4 Dermal H312 Skin Irrit 2 H315 Eye Dam 1 H318 Aquatic Acute 1 H400 Aquatic Chronic 2 H411 Met Corr 1 H290 Skin Corr 1A H314 Eye Dam 1 H318 STOT SE 3 H335 Aquatic Acute 2 H401 Full text of H phrases see Section 16 SECTION 4 FIRST AID MEASURES 4 1 Description of First aid Measures 4 2 Most Important Symptoms and Effects Both Acute and Delayed 4 3 Indication of Any Immediate Medical Attention and Special Treatment Needed First aid Measures General Never give anything by mouth to an unconscious person If you feel unwell seek medical advice show the label where possible First aid Measures After Inhalation When symptoms occur go into open air and ventilate suspected area Obtain medical attention if breathing difficulty persists First aid Measures After Skin Contact Remove contaminated clothing Drench affected area with water for at least 15 minutes Obtain medical attention if irritation develops or persists First aid Measures After Eye Contact Rinse cautiously with water for at least 30 minutes Remove contact lenses if present and easy to do Continue rinsing Seek immediate medical advice attention First aid Measures After Ingestion Rinse mouth Do NOT induce vomiting Obtain medical attention Symptoms Injuries Causes skin irritation Causes serious eye damage Symptoms Injuries After Inhalation Prolonged exposure may cause irritation Symptoms Injuries After Skin Contact Redness pain swelling itching burning dryness and dermatitis Symptoms Injuries After Eye Contact Causes permanent damage to the cornea iris or conjunctiva Symptoms Injuries After Ingestion Ingestion may cause adverse effects Chronic Symptoms None expected under normal conditions of use If exposed or concerned get medical advice and attention If medical advice is needed have product container or label at hand SECTION 5 FIRE FIGHTING MEASURES 5 1 Extinguishing Media 5 2 Special Hazards Arising From the Substance or Mixture 5 3 Advice for Firefighters Suitable Extinguishing Media Water spray dry chemical foam carbon dioxide Unsuitable Extinguishing Media Do not use a heavy water stream Use of heavy stream of water may spread fire Fire Hazard Not considered flammable but may burn at high temperatures Explosion Hazard Contact with metallic substances may release flammable hydrogen gas Reactivity May be corrosive to metals Contact with metals may evolve flammable hydrogen gas Precautionary Measures Fire Exercise caution when fighting any chemical fire Firefighting Instructions Use water spray or fog for cooling exposed containers Protection During Firefighting Do not enter fire area without proper protective equipment including respiratory protection Hazardous Combustion Products Hydrogen chloride Lithium oxides SECTION 6 ACCIDENTAL RELEASE MEASURES 6 1 Personal Precautions Protective Equipment and Emergency Procedures General Measures Do not breathe vapor mist or spray Do not get in eyes on skin or on clothing 6 1 1 For Non Emergency Personnel Protective Equipment Use appropriate personal protective equipment PPE Emergency Procedures Evacuate unnecessary personnel 11 09 2018 EN English US 2 7
Chlorine Electrolyte Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations 6 1 2 For Emergency Personnel Protective Equipment Equip cleanup crew with proper protection Emergency Procedures Upon arrival at the scene a first responder is expected to recognize the presence of dangerous goods protect oneself and the public secure the area and call for the assistance of trained personnel as soon as conditions permit Ventilate area 6 2 Environmental Precautions 6 3 Methods and Materials for Containment and Cleaning Up 6 4 Reference to Other Sections Prevent entry to sewers and public waters For Containment Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams Methods for Cleaning Up Clean up spills immediately and dispose of waste safely Transfer spilled material to a suitable container for disposal Contact competent authorities after a spill Absorb spillage to prevent material damage See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations SECTION 7 HANDLING AND STORAGE 7 1 Precautions for Safe Handling 7 2 Conditions for Safe Storage Including Any Incompatibilities 7 3 Specific End Use s Additional Hazards When Processed May be corrosive to metals Precautions for Safe Handling Wash hands and other exposed areas with mild soap and water before eating drinking or smoking and when leaving work Avoid breathing vapors mist spray Do not get in eyes on skin or on clothing Hygiene Measures Handle in accordance with good industrial hygiene and safety procedures Technical Measures Comply with applicable regulations Storage Conditions Keep container closed when not in use Store in a dry cool place Keep Store away from direct sunlight extremely high or low temperatures and incompatible materials Store in corrosive resistant container with a resistant inner liner Incompatible Materials Metals May be corrosive to metals Strong acids strong bases strong oxidizers water reactive materials Packaging materials Store in corrosive resistant container or with a resistant inner liner Industrial Use SECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION 8 1 Control Parameters 8 2 Exposure Controls For substances listed in Section 3 that are not listed here there are no established exposure limits from the manufacturer supplier importer or the appropriate advisory agency including ACGIH TLV AIHA WEEL NIOSH REL or OSHA PEL Hydrochloric acid 7647 01 0 USA ACGIH ACGIH Ceiling ppm 2 ppm USA ACGIH ACGIH chemical category Not Classifiable as a Human Carcinogen USA NIOSH NIOSH REL ceiling mg m 7 mg m USA NIOSH NIOSH REL ceiling ppm 5 ppm USA IDLH US IDLH ppm 50 ppm USA OSHA OSHA PEL Ceiling mg m 7 mg m USA OSHA OSHA PEL Ceiling ppm 5 ppm Appropriate Engineering Controls Personal Protective Equipment Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure Ensure adequate ventilation especially in confined areas Ensure all national local regulations are observed Gloves Protective clothing Protective goggles Materials for Protective Clothing Hand Protection Eye and Face Protection Skin and Body Protection 11 09 2018 Chemically resistant materials and fabrics Wear protective gloves Chemical safety goggles Wear suitable protective clothing EN English US 3 7
Chlorine Electrolyte Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Respiratory Protection Other Information If exposure limits are exceeded or irritation is experienced approved respiratory protection should be worn In case of inadequate ventilation oxygen deficient atmosphere or where exposure levels are not known wear approved respiratory protection When using do not eat drink or smoke SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 9 1 Information on Basic Physical and Chemical Properties 9 2 Other Information Physical State Appearance Odor Odor Threshold pH Evaporation Rate Melting Point Freezing Point Boiling Point Flash Point Auto ignition Temperature Decomposition Temperature Flammability solid gas Vapor Pressure Relative Vapor Density at 20 C Relative Density Solubility Partition Coefficient N Octanol Water Viscosity Liquid No data available No data available No data available 1 No data available No data available No data available No data available No data available No data available No data available Not applicable No data available No data available No data available No data available No data available No data available No additional information available SECTION 10 STABILITY AND REACTIVITY 10 1 Reactivity May be corrosive to metals Contact with metals may evolve flammable hydrogen gas 10 2 Chemical Stability Stable under recommended handling and storage conditions see Section 7 10 3 Possibility of Hazardous Reactions Hazardous polymerization will not occur 10 4 Conditions to Avoid Direct sunlight extremely high or low temperatures and incompatible materials 10 5 Incompatible Materials Metals May be corrosive to metals Strong acids strong bases strong oxidizers water reactive materials 10 6 Hazardous Decomposition Products None expected under normal conditions of use SECTION 11 TOXICOLOGICAL INFORMATION 11 1 Information on Toxicological Effects Acute Toxicity Not classified Lithium chloride 7447 41 8 LD50 Oral Rat 526 mg kg LD50 Dermal Rat 2000 mg kg LC50 Inhalation Rat 5 57 mg l 4h Copper 2 chloride dihydrate 10125 13 0 ATE Oral 500 00 mg kg body weight ATE Dermal 1 100 00 mg kg body weight Hydrochloric acid 7647 01 0 LD50 Dermal Rabbit 5010 mg kg Skin Corrosion Irritation Causes skin irritation pH 1 Serious Eye Damage Irritation Causes serious eye damage pH 1 11 09 2018 EN English US 4 7
Chlorine Electrolyte Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Respiratory or Skin Sensitization Not classified Germ Cell Mutagenicity Not classified Carcinogenicity Not classified Hydrochloric acid 7647 01 0 IARC group 3 Reproductive Toxicity Not classified Specific Target Organ Toxicity Single Exposure Not classified Specific Target Organ Toxicity Repeated Exposure Not classified Aspiration Hazard Not classified Symptoms Injuries After Inhalation Prolonged exposure may cause irritation Symptoms Injuries After Skin Contact Redness pain swelling itching burning dryness and dermatitis Symptoms Injuries After Eye Contact Causes permanent damage to the cornea iris or conjunctiva Symptoms Injuries After Ingestion Ingestion may cause adverse effects Chronic Symptoms None expected under normal conditions of use SECTION 12 ECOLOGICAL INFORMATION 12 1 Toxicity Ecology General Lithium chloride 7447 41 8 LC50 Fish 1 Hydrochloric acid 7647 01 0 LC50 Fish 1 12 2 Report spills to the competent authority as this material is strongly acidic 17 mg l 7 45 mg l Species Oncorhynchus mykiss Exposure time 96h Persistence and Degradability Chlorine Electrolyte Persistence and Degradability 12 3 Not established Bioaccumulative Potential Chlorine Electrolyte Bioaccumulative Potential Lithium chloride 7447 41 8 BCF Fish 1 Log Pow 12 4 Mobility in Soil 12 5 Other Adverse Effects Not established no bioaccumulation 2 66 No additional information available Other Information SECTION 13 DISPOSAL CONSIDERATIONS 13 1 Avoid release to the environment Waste Treatment Methods Waste Disposal Recommendations Dispose of contents container in accordance with local regional national and international regulations Additional Information Container may remain hazardous when empty Continue to observe all precautions Ecology Waste Materials Avoid release to the environment SECTION 14 TRANSPORT INFORMATION The shipping description s stated herein were prepared in accordance with certain assumptions at the time the SDS was authored and can vary based on a number of variables that may or may not have been known at the time the SDS was issued 14 1 In Accordance with DOT Proper Shipping Name Hazard Class Identification Number Label Codes Packing Group ERG Number III 154 Proper Shipping Name Hazard Class CORROSIVE LIQUID ACIDIC INORGANIC N O S COPPER CHLORIDE HYDROCHLORIC ACID 8 14 2 11 09 2018 CORROSIVE LIQUID ACIDIC INORGANIC N O S COPPER CHLORIDE HYDROCHLORIC ACID 8 UN3264 8 In Accordance with IMDG EN English US 5 7
Chlorine Electrolyte Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Identification Number Packing Group Label Codes EmS No Fire EmS No Spillage 14 3 UN3264 III 8 F A S B In Accordance with IATA Proper Shipping Name Packing Group Identification Number Hazard Class Label Codes ERG Code IATA 8L CORROSIVE LIQUID ACIDIC INORGANIC N O S COPPER CHLORIDE HYDROCHLORIC ACID III UN3264 8 8 This product meets the limited quantities exception as follows DOT Not regulated as dangerous goods except when transported by air or shipped in quantities greater than or equal to the limited quantity Otherwise the above descriptions apply SECTION 15 REGULATORY INFORMATION 15 1 US Federal Regulations Chlorine Electrolyte SARA Section 311 312 Hazard Classes Physical hazard Corrosive to metals Health hazard Serious eye damage or eye irritation Health hazard Skin corrosion or Irritation Lithium chloride 7447 41 8 Listed on the United States TSCA Toxic Substances Control Act inventory Water 7732 18 5 Listed on the United States TSCA Toxic Substances Control Act inventory Hydrochloric acid 7647 01 0 Listed on the United States TSCA Toxic Substances Control Act inventory Listed on the United States SARA Section 302 Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 5000 lb SARA Section 302 Threshold Planning Quantity TPQ 500 lb gas only SARA Section 313 Emission Reporting 1 acid aerosols including mists vapors gas fog and other airborne forms of any particle size 15 2 US State Regulations Hydrochloric acid 7647 01 0 U S Massachusetts Right To Know List U S New Jersey Right to Know Hazardous Substance List U S Pennsylvania RTK Right to Know Environmental Hazard List U S Pennsylvania RTK Right to Know List SECTION 16 OTHER INFORMATION INCLUDING DATE OF PREPARATION OR LAST REVISION Date of Preparation or Latest Revision Other Information 05 03 2018 This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910 1200 GHS Full Text Phrases Acute Tox 4 Dermal Acute Tox 4 Oral Aquatic Acute 1 Aquatic Acute 2 Aquatic Acute 3 Aquatic Chronic 2 Eye Dam 1 Eye Irrit 2A 11 09 2018 Acute toxicity dermal Category 4 Acute toxicity oral Category 4 Hazardous to the aquatic environment Acute Hazard Category 1 Hazardous to the aquatic environment Acute Hazard Category 2 Hazardous to the aquatic environment Acute Hazard Category 3 Hazardous to the aquatic environment Chronic Hazard Category 2 Serious eye damage eye irritation Category 1 Serious eye damage eye irritation Category 2A EN English US 6 7
Chlorine Electrolyte Safety Data Sheet According to Federal Register Vol 77 No 58 Monday March 26 2012 Rules and Regulations Met Corr 1 Skin Corr 1A Skin Irrit 2 STOT SE 3 H290 H302 H312 H314 H315 H318 H319 H335 H400 H401 H402 H411 Corrosive to metals Category 1 Skin corrosion irritation Category 1A Skin corrosion irritation Category 2 Specific target organ toxicity single exposure Category 3 May be corrosive to metals Harmful if swallowed Harmful in contact with skin Causes severe skin burns and eye damage Causes skin irritation Causes serious eye damage Causes serious eye irritation May cause respiratory irritation Very toxic to aquatic life Toxic to aquatic life Harmful to aquatic life Toxic to aquatic life with long lasting effects This information is based on our current knowledge and is intended to describe the product for the purposes of health safety and environmental requirements only It should not therefore be construed as guaranteeing any specific property of the product SDS US GHS HazCom False 11 09 2018 EN English US 7 7