Hybrid excitations due to crystal field spin orbit coupling and spin waves in LiFePO4 Yuen Yiua Manh Duc Leb Rasmus Toft Petersonc Georg Ehlersd Robert McQueeneya and David Vaknina a DMSE Ames Laboratory and Department of Physics and Astronomy Iowa State University USA b ISIS Neutron and Muon Source Rutherford Appleton Laboratory UK c Helmholtz Zentrum Berlin f ur Materialen und Energie Germany d Quantum Condensed Matter Division Oak Ridge National Laboratory USA Dated August 4 2016 We report on the spin waves and crystal field excitations in single crystal LiFePO4 by inelastic neutron scattering over a wide range of temperatures below and above the antiferromagnetic transition of this system In particular we find extra excitations below TN 50 K that are nearly dispersionless and are most intense around magnetic zone centers We show that these excitations correspond to transitions between thermally occupied excited states of Fe2 due to splitting of the S 2 levels that arise from crystal field and spin orbit interaction These excitations are further amplified by the highly distorted nature of the oxygen octahedron surrounding the iron atoms Above TN magnetic fluctuations are observed up to at least 720 K with an additional excitation broad in energy is observed around 4 meV likely caused by single ion splittings through spin orbit and crystal field interactions The latter weakens slightly at 720 K compared to 100 K which is consistent with calculated cross sections using a single ion model Our theoretical analysis using the MF RPA model provides both detailed spectra of the Fe d shell and estimates of the average ordered magnetic moment and TN By applying the MF RPA model to a number of existing spin wave results from other LiM PO4 M Mn Co and Ni we are able to obtain reasonable predictions for the moment sizes and transition temperatures I INTRODUCTION Various members of the lithium orthophosphates have gained renewed attention in the last decade as candidates of electrodes in lithium based rechargeable batteries1 4 by virtue of their high Li ion conductivity through channels that are present in their olivine crystal structure1 5 6 Thus although most research efforts have recently been focused on their electro chemical properties they have long been known to exhibit intriguing magnetic properties In particular the transition metal based lithiumorthophosphates display strong magnetoelectric ME effect where an applied magnetic field induces an electric polarization and vice versa applied electric field induces magnetization Naturally the ME effect is invoked by the coupling among orbital magnetic and electrostatic degrees of freedom that have been at the forefront of recent research in condensed matter physics Prominent examples of such coupling have been found in the iron and copper based unconventional superconductors7 8 the giant magnetoresistance in Mn based oxides9 10 or the magnetoelectric effect in transition metal oxides11 12 Often interrelated magnetic electric and or structural transformations raise the question of their origin but it is generally accepted that the spin orbit coupling SOC drives a secondary transition namely magnetic or structural that follows structural or magnetic respectively The SOC can also lead to higher order asymmetric exchange terms such as the Dzyaloshinskii Moriya interaction and can lift the degeneracy of crystal field levels In the case of the lithium orthophosphates it has been observed that the relative strength of the ME effect correlates with the effective total orbital moment with LiCoPO4 L 3 and LiMnPO4 L 0 displaying the largest and smallest ME coefficients13 16 Here we report on the magnetic excitations of LIFePO4 and expand on recent elastic and inelastic neutron studies of the lithium orthophosphates17 19 Similar to other lithiumorthophosphates LiFePO4 possesses an intricate magnetic structure where the Fe2 moments S 2 L 2 order antiferromagnetically at TN 50 K with moments pointing mainly along the b direction20 21 However subsequent studies have revealed zero field spin canting along a and c which are both forbidden by Pnma symmetry hinting that the crystal structure symmetry might be lower than Pnma below TN 22 The observed spin canting implies the presence of Dzyaloshinsky Moriya DM interactions which can be linked to the ME response The local symmetry of the magnetically ordered Fe sublattice may also be reflected by the crystal field level structure of Fe2 23 Several inelastic neutron scattering INS efforts have measured the spin wave spectrum in LiFePO4 in restricted regions of the Brillouin zone22 24 The most comprehensive model for LiFePO4 deduced from these measurements includes 5 exchange interaction terms 1 in plane nearest neighbour 2 in plane next nearestneighbours and 2 out of plane interactions and 2 single ion anisotropy terms along a and c In this study we complete the INS picture for spin waves measured along all directions a b and c and compare our results with the existing Hamiltonian We also report on new
Hybrid excitations due to crystal-field, spin-orbit coupling and spin-waves in LiFePO4 Yuen Yiua , Manh Duc Leb , Rasmus T...
2 low energy excitations found below the spin waves excitations which persist from below TN up to 720 K We argue that such excitations are due to single ion splitting of the S 2 manifold from the crystal field spin orbit and ordered moment exchange field Modifications of the existing spin Hamiltonian model will include these hybrid excitations that account for those new excitations II EXPERIMENTAL DETAILS For the inelastic neutron scattering experiment a single crystalline sample of LiFePO4 was used The crystal was selected from a batch of single crystals synthesized using the standard flux growth method using the same recipe prescribed by Ref 22 The high quality single crystal weighs approximately 200mg and its structure and stoichiometry were confirmed by laboratory X ray and by single crystal neutron diffraction22 Inelastic neutron scattering INS data were collected at the Cold Neutron Chopper Spectrometer CNCS 25 of the Spallation Neutron Source Oak Ridge National Laboratory The sample was aligned with the bc plane horizontal with some detector coverage along the a vertical direction The incident neutron energy was set at Ei 12 meV for the optimal resolution and flux for the Q region of relevant interest INS data was collected at three separate temperatures T 35 100 and 720 K III RESULTS AND DISCUSSION Figure 1 a c shows contour plots of the INS data collected at T 35 K along the H10 0K0 and 00L reciprocal space directions with an incident neutron energy of Ei 12 meV and integrated over a range of Q of 0 25 reciprocal lattice units Along 0K0 two spin wave branches are clearly visible as expected by the known antiferromagnetic structure which contains spins precessing perpendicular to the moment direction b22 One branch where the two oppositely aligned spins precess in phase and one branch where the two precess outof phase Also shown in Fig 1 are dotted lines obtained from linear spin wave calculations using the existing spin Hamiltonian described below22 1X H Jij Si Sj HSIA 1 2 i j The Hamiltonian considers 5 exchange interaction terms among them are one nearest neighbor Jbc two next nearest neighbors Jb and Jc and two out of plane interactions Jab and Jac Previous reports based on single crystal data have found magnetic anisotropy along a and c20 24 and as a result the Hamiltonian requires the inclusion of single ion anisotropy SIA terms Da and Dc allowing for an anisotropic hard plane while the easy axis b direction is set by Db 0 For the linear spin wave calculation shown here the J and D values from previously published inelastic single crystal data of the same crystal are used22 These values are listed in Table I TABLE I Exchange interactions Jij and single ion anisotropy Da and Dc in meV used in calculating the spin waves shown in Fig 1 Hmf is calculated from the Jij s in the mean field approximation Fig 1 a c Fig 1 d f Ref 22 this study Jbc 0 77 2 0 46 2 Jb 0 30 2 0 09 1 Jc 0 14 2 0 01 1 Jab 0 14 2 0 09 1 Jac 0 05 1 0 01 1 Da 0 62 1 0 86 2 Dc 1 56 4 2 23 2 Hmf 4 84 3 69 A Zeeman splitting As illustrated in Fig 1 a c the linear spin wave calculations white dotted lines track the measured magnon dispersion closely however it does not account for the extra excitations visible near 4 5 meV indicated by the red arrows These extra excitations are nearly dispersionless in energy and centered around the magnetic zone centers We argue that these extra excitations arise from transitions from a thermally populated excited state of the spin S 2 multiplet that are not considered by spin wave theory which is a T 0 theory and maps the spin ground state to a vacuum state and transitions from to this state to from the nth excited state to creation annihilation of n magnons The 4 5 meV excitation corresponds to a transition between two excited states n 1 and n 2 as illustrated schematically in Fig 2 We thus use the mean field random phase approximation MF RPA 26 to calculate the higher temperature magnetic spectrum Fig 2 shows schematically how the different singleion interactions splits the d electron energy levels The largest energy splitting of the order of an electron volt is from the crystal field which only acts on the orbital angular momentum leaving the spin states degenerate In the lithium orthophosphates the Fe2 ions are located at a low monoclinic Cs symmetry site so the crystal field splitting lifts all orbital degeneracy resulting in five orbital singlets which each have a five fold spin degeneracy The on site spin orbit interaction is much weaker than the crystal field interaction in transition metals and only splits the spin states by a few meV Finally in the ordered phase the ordered moments generate a internal magnetic field which further Zeeman splits the spin energy levels The effects of the spin orbit and crystal field interactions on the S 2 levels can be parameterised by
2 low-energy excitations found below the spin waves excitations, which persist from below TN up to 720 K. We argue that su...
3 FIG 1 color online a c Contour plots of energy transfer from the inelastic neutron scattering INS data collected at T 35 K along H10 0K0 and 00L The dashed lines are calculated linear spin wave dispersions based on the model described in the text The red arrows indicate extra excitations visible around 4 5 meV that corresponds to Zeeman splitting levels by internal mean field induced by the ordered moments d f Virtual INS data calculated based on the same model using mean field random phase approximation As can be seen the simulation correctly predicts the hybrid extra excitations near 4 5 meV in addition to an extra less intense excitation near 3 meV both originating from internal Zeeman splitting the single ion anisotropy parameters Da and Dc whilst the Heisenberg term leads to a Zeeman like interaction in the mean field MF approximation Thus we can rewrite equation 1 in the MF approximation as an effective single ion Hamiltonian 1 Hmf HSIA HZeeman 2 where after choosing the moment direction as the quantisation axis that is z b HSIA Da S x2 Dc S y2 HZeeman Hmf S z 3 4 where Da Dc and Hmf which depends on the Jij parameters are given in Table I Diagonalising this Hamiltonian in the Sz i basis with the Zeeman term results in the level scheme shown in Table II for the ordered AFM phase whereas setting Hmf 0 gives the level scheme shown for the paramagnetic phase Furthermore inspection of the results of diagonalising the Hamiltonian with different values of Da Dc and Hmf shows that when Hmf Da Dc the difference in energy between the n 1 and n 2 levels is 12 Hmf Da Dc 2 The parameters given in Table I are determined by fitting the measured data at 35 K using the MF RPA as im TABLE II Calculated level scheme due to the crystal field and spin orbit interactions parameterized by the single ion parameters Da 0 86 Dc 2 23 meV in the paramagnetic phase and in the magnetically ordered phase with an additional Zeeman splitting term parameterised by Hmf 3 69 meV Energy meV Sz i components Paramagnetic Phase n 0 0 0 67 2i 2i 0 32 0i 1 0 81 1 2 2i 2i 2 3 39 1 2 1i 1i 3 7 49 1 2 1i 1i 4 7 79 0 23 2i 2i 0 95 0i Ordered Phase n 0 0 0 99 2i 0 12 0i 1 8 00 0 97 1i 0 25 1i 2 12 73 0 80 0i 0 60 2i 3 16 21 0 80 2i 0 60 0i 4 16 45 0 97 1i 0 25 1i plemented in the program M cP hase27 29 within the data analysis environment provided by the program Horace30 In order to find starting parameters for the fit we generate 105 random sets of exchange Jij and single ion anisotropy D parameters and then use the previously
3  FIG. 1.  color online   a-c   Contour plots of energy transfer from the inelastic neutron scattering  INS  data collect...
4 FIG 2 color online Multi electron states arising from the crystal field splitting each of these orbital singlets has a fivefold spin degeneracy The ground state multiplet is further split as indicated by the blue lines either by spin orbit coupling or internal magnetic field when the system is magnetically ordered reported 2 K data and linear spin wave model22 to filter out parameter sets which do not reproduce the low temperature dispersion This procedure produces several sets of parameters which differ from the published set by having smaller Jij but larger D parameters which although having slightly higher 2 values still fit the 2 K data well This is because the calculated spin wave bandwidth and energy gap are governed by both the Jij and D parameters in a complex fashion so that the same bandwidth and gap can result from smaller Jij and larger D parameters However as Hmf is determined by the exchange parameters Jij and has a larger effect on the energy 12 of the excited state transition weaker Jij parameters fit the 35 K measurements better as the Hmf from the parameters of Ref 22 overestimates the energy of the excited state mode Furthermore the MF RPA predicts the physical properties better since the calculated transition temperature in the mean field approximation is TNmf 73 K for the parameters of Ref 22 compared to TNmf 62 K for the set obtained from the fit of the neutron spectrum at 35 K as presented in Fig 1 d f The calculated spectrum gives four excitation branches at 35 K rather than the three observed The fourth mode calculated to have an energy of 3 7 meV corresponds to an excited state transition from the n 2 to the n 4 level and is expected to have one fifth the intensity of the 4 5 meV excitation from n 1 to n 2 with a calculated cross section of 7 mb sr Fe2 compared to 36 mb sr Fe2 Thus it is probably too weak to be observed experimentally Inspection of the fitted exchange parameters show that the nearest neighbour superexchange interaction Jbc be tween Fe2 ions via a single oxygen ligand is more dominant than previously thought with Jbc Jb 5 this study rather than Jbc Jb 2 5 previous study22 Furthermore Jb and Jab have similar magnitudes and are both larger than Jc and Jac which are extremely weak but non zero These next nearest neighbour interactions are mediated by superexchange via two oxygen ligands but whilst Jc and Jac couple Fe2 ions lying in octahedra which are tilted in opposite directions giving Fe O O Fe bond angles closer to 90 the FeO6 octahedra linked by Jb and Jab are tilted in the same direction resulting in more obtuse bond angles and hence greater overlap for the oxygen p orbitals However a potential shortfall of modeling the spinorbit and crystal field interactions using the effective SIA parameters Da and Dc is that it ignores higher order and odd component crystal field terms which are permitted here because of the low symmetry of the crystallographic site occupied by the Fe2 ions Using the full crystal field Hamiltonian i HCF Li Si k X X Bkq Okq 5 k 2 4 q k in place of HSIA requires many more parameters including on site spin orbit coupling and the crystal field parameters Bkq We choose to restrict 12 75 meV to the free ion value determined by optical spectroscopy and atomic calculations31 32 and use the point charge model to determine the Bkq parameters including charges within a cutoff range of 3 3 A from the Fe2 ions The point charge model has known shortcomings such as not accounting for charge transfer or bonding effects but allows us to reduce the number of parameters to three the effective charges on each ligand atomic species Starting parameters are obtained by requiring the point charges to approximately reproduce the energy level scheme in Table II Fitting the 35 K inelastic dataset with this new point charge model we obtained qO 1 87 3 e for the oxygen ligands qP 0 58 3 e for the phosphorous and qLi 0 04 2 e for the lithium Thus it seems that the flowing Li ions contribute very little to the anisotropy of the iron spins as may be expected whilst the largest effect is due to the distorted oxygen octahedron The calculations does give the b direction as the easy direction but overestimates the ordered moment calc 4 67 B compared to a measured value of 4 09 4 B 22 More importantly the calculated inelastic neutron spectrum is virtually identical to that shown in Fig 1 df using the SIA parameters Da and Dc Thus the higher order crystal field terms appear to have little effect on the dispersion or intensities of the spin waves or excited state transition This can be understood by reference to Table II where we see that the ground state n 0 and the first excited state n 1 are both nearly pure states that is the n 0 state is 99 Sz 2i and the n 1 state is 98 Sz 1i so the wavefunctions and hence the transition matrix elements which deter
4  FIG. 2.  color online  Multi-electron states arising from the crystal field splitting, each of these orbital singlets h...
5 FIG 3 Energy transfer at 010 and 001 for T 35 and 100 K The integrated Q range is 0 25 along each direction The red arrows indicates the extra excitation observed near 4 meV for 35 K along both directions The thick red bar represents approximately the instrumental resolution width mine dispersion and scattering intensity are dominated by the ordered phase Zeeman field TABLE III Calculated and reported moment directions and sizes for LiM PO4 Calculations for Co33 Ni17 and Mn19 are based on reported values of exchange parameters Note that for small amount of canting is present in LiFePO4 but has been omitted here22 M Calc moment Exp moment a b c in B a b c in B Fe 0 4 67 0 0 4 09 0 22 34 Co 0 3 87 0 0 3 35 0 35 Ni 0 41 0 2 80 0 3 0 2 2 17 Mn 5 00 0 0 4 29 0 0 19 36 Nonetheless the point charge model does show us that the b easy axis direction and anisotropic hard plane can be explained by the distorted geometry of the oxygen octahedron surrounding the Fe2 spins Indeed applying the same point charge model as fitted to the inelastic neutron scattering data from LiFePO4 to other lithiumorthophosphates satisfactorily reproduces the measured ordered moment directions in LiM PO4 although the magnitude of the ordered moments are overestimated by MF RPA Table III provide a list of magnetic moment sizes and orientations calculated using the point charge model with comparison to the reported values for LiM PO4 M Fe Co Ni and Mn B Spin orbit splitting Fig 3 shows the energy responses of INS intensity around 010 and 001 at T 35 and 100 K In order to correctly analyze the energy response the negative energy transfer portion i e neutron energy gain of the FIG 4 a Measured energy transfer at 010 for T 100 296 and 720 K The dashed lines show the fitted Lorentzian centered at E 0 and a Gaussian centered near 4 meV The solid colored lines show the sum of the fitted Lorentzian and Gaussian curves b Calculated energy transfer at 010 for the same temperatures data have been processed using the principle of detailed balance37 The spectrum at T 35 K which is below TN and in the spin ordered phase shows well defined peaks that correspond to the spin wave branches The red arrows indicate the extra excitations observed near 4 5 meV as shown above Above TN 50K the system becomes paramagnetic and both the magnon dispersions and the hybrid 4 5 meV excitation disappear Fig 4 a shows a closer look of the INS energy responses at higher temperatures 100 296 and 720 K At these temperatures the spectra are relatively broad in energy which includes a Lorentzian component centering at 0 meV and a Gaussian component centering near 4 meV all represented as dashed lines in Fig 4 a The Lorentzian response is expected of magnetic fluctuations that are quasi elastic in nature and short lived in time however there is little change in intensity and width over a temperature range many times TN Broad excitations are detected around 3 4 4 meV at 100 K and 4 2 7 meV at 720 K determined by the fitted Gaussian curves as represented by the two dashed Gaussian lines in Fig 4 a Since the internal fields generated by the ordered moments should be absent at these temperatures these excitations cannot be the same excited state excitation discussed above seen at 35 K However as shown in Table II in the paramagnetic phase the spin orbit and crystal field interactions combined still splits the S 2 levels for instance the energy for a n 2 to 0 transition is 3 39 meV which may be what is observed at 100 K At 720 K we should expect that all the
5  FIG. 3. Energy transfer at  010  and  001  for T   35 and 100 K. The integrated Q range is   0.25 along each direction....
6 excited states have become populated allowing higher transitions to have greater spectral weight and shifting the observed peak to a higher energy However the data is much broader than the instrumental resolution and MF RPA theory we have used to analyse the low temperature data does not account for thermal broadening of the excitations Instead we have convoluted the calculation with Gaussian curves with a full width at half maximum of 1 2 meV to obtain the curves in figure 4 whereas instrumental resolution at these energy transfers is expected to be less than 0 5 meV It can be seen that this still does not fully account for the measurements In addition the calculations predict that the intensity should fall off much faster with increasing temperature than is observed the calculate intensity ratio of the peak area at 720 K vs 100 K is 0 35 which is half that observed I720K I100K 0 7 Thus whilst the energies of the peaks observed at high temperatures may be satisfactorily explained by the MF RPA theory their intensity and linewidths needs a more sophisticated approach Fe2 due to splitting of the S 2 levels that arise from the effects of the crystal field and spin orbit interactions amplified by the highly distorted nature of the oxygen octahedron surrounding the iron spins Above TN the magnetic fluctuations are observed to relatively high temperatures with little temperature dependence between 100 and 720 K Additional excitations broad in energy are observed around 4 meV that are due to the single ion splittings caused by the spin orbit and crystal field interactions These excitations weaken slightly at 720 K compared to 100 K consistent with the calculated crosssections from our single ion model Our theoretical analysis using the MF RPA model provides detailed spectra of the d shell in LiFePO4 and also enables estimates of the average ordered magnetic moment and TN Applying it to spin wave results of other members of the LiM PO4 M Mn Co and Ni compounds provides reasonable ordered moments and transition temperatures showing the approach is robust V IV SUMMARY In summary we present a inelastic neutron scattering study in LiFePO4 that complements a previous spin wave excitations study In particular we find an extra excitation at 4 5 meV at T 35 K TN that is nearly dispersionless and is most intense around magnetic zone centers We show that these excitations correspond to transitions between thermally occupied excited states of 1 2 3 4 5 6 7 8 9 10 11 12 13 M Park X Zhang M Chung G B Less and A M Sastry Journal of Power Sources 195 7904 2010 A Padhi K Nanjundaswamy and J Goodenough Journal of the Electrochemical Society 144 1188 1997 S Chung J Bloking and Y Chiang Nature Materials 1 123 2002 J Thomas Nature Materials 2 705 2003 J Yang and J S Tse Journal of Physical Chemistry A 115 13045 2011 S i Nishimura G Kobayashi K Ohoyama R Kanno M Yashima and A Yamada Nature Materials 7 707 2008 P Dai J Hu and E Dagotto Nature Physics 8 709 2012 D C Johnston Advances in Physics 59 803 2010 W Pickett and D Singh Physical Review B 53 1146 1996 A Ramirez Journal of Physics Condensed Matter 9 8171 1997 C W Nan M I Bichurin S Dong D Viehland and G Srinivasan Journal of Applied Physics 103 2008 J Li W Yao S Martin and D Vaknin Solid State Ionics 179 2016 2008 J P Rivera Ferroelectrics 161 147 1994 ACKNOWLEDGEMENT We thank Jens Jensen for very detailed and fruitful discussions Research at Ames Laboratory is supported by the U S Department of Energy Office of Basic Energy Sciences Division of Materials Sciences and Engineering under Contract No DE AC02 07CH11358 Use of the Spallation Neutron Source at the Oak Ridge National Laboratory is supported by the U S Department of Energy Office of Basic Energy Sciences Scientific Users Facilities Division 14 15 16 17 18 19 20 21 22 J P Rivera and H Schmid Ferroelectrics 161 91 1994 D Vaknin J L Zarestky L L Miller J P Rivera and H Schmid Phys Rev B 65 224414 2002 M Mercier These de doctorat d Etat Ph D thesis Faculte des Sciences Universite de Grenoble France 1969 T B S Jensen N B Christensen M Kenzelmann H M R nnow C Niedermayer N H Andersen K Lefmann J Schefer M v Zimmermann J Li J L Zarestky and D Vaknin Physical Review B 79 092412 2009 R Toft Petersen J Jensen T B S Jensen N H Andersen N B Christensen C Niedermayer M Kenzelmann M Skoulatos M D Le K Lefmann S R Hansen J Li J L Zarestky and D Vaknin Physical Review B 84 2011 R Toft Petersen N H Andersen H Li J Li W Tian S L Bud ko T B S Jensen C Niedermayer M Laver O Zaharko J W Lynn and D Vaknin Physical Review B 85 224415 2012 G Liang K Park J Li R E Benson D Vaknin J T Markert and M C Croft Physical Review B 77 2008 R P Santoro and R E Newnham Acta Crystallographica 22 344 1967 R Toft Petersen M Reehuis T B S Jensen N H Andersen J Li M D Le M Laver C Niedermayer
6 excited states have become populated, allowing higher transitions to have greater spectral weight, and shifting the obse...
7 23 24 25 26 27 28 29 B Klemke K Lefmann and D Vaknin Physical Review B 92 2015 Y Xiao M Zbiri R A Downie J W G Bos T Br uckel and T Chatterji Physical Review B 88 214419 2013 J Li V Garlea J Zarestky and D Vaknin Physical Review B 73 2006 G Ehlers A A Podlesnyak J L Niedziela E B Iverson and P E Sokol Review of Scientific Instruments 82 2011 J Jensen and A R Mackintosh Rare Earth Magnetism Structures and Excitations Clarendon Press Oxford 1991 R M Journal of Magnetism and Magnetic Materials 272 E481 2004 M Rotter S Kramp M Loewenhaupt E Gratz W Schmidt N Pyka B Hennion and R v d Kamp Applied Physics A 74 s751 M Rotter M D Le A T Boothroyd and J A Blanco Journal of Physics Condensed Matter 24 213201 2012 30 31 32 33 34 35 36 37 R A Ewings A Buts M D Le J van Duijn I Bustinduy and T G Perring arXiv 1604 05895 2016 A Chakravarty Introduction to the Magnetic Properties of Solids John Wiley and Sons 1980 T Dunn The Faraday Society and Contributors 1441 1961 W Tian J Li J W Lynn J L Zarestky and D Vaknin Physical Review B 78 184429 2008 G Rousse J Rodriguez Carvajal S Patoux and C Masquelier Chemistry of Materials 15 4082 2003 R Toft Petersen Magnetic structures of the lithium orthophosphates and the study of the Bragg glass phase of vortex matter Ph D thesis Danmarks Tekniske Universitet Ris Nationallaboratoriet for B redygtig Energi 2011 C M Julien A Ait Salah A Mauger and F Gendron Ionics 12 21 2006 N Berk Journal of Research of the National Institute of Standards and Technology 98 15 1993
7  23  24  25  26  27  28  29  B. Klemke, K. Lefmann, and D. Vaknin, Physical Review B 92  2015 . Y. Xiao, M. Zbiri, R. A....